ESTONIAN ACADEMY
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Estonian Journal of Ecology
Grain-size analysis of lacustrine sediments: a comparison of pre-treatment methods; pp. 231–243
PDF | doi: 10.3176/eco.2008.4.01

Author
Tiit Vaasma
Abstract

This study presents the results of an experimental investigation of five different pre-treatment methods for measuring the grain-size distribution of allochthonous siliclastic matter in cohesive organic-rich sediments and some comparisons with mineral-rich sediments. The loss on ignition (LOI) methods were the fastest for eliminating organic matter but here a problem of aggregate formation may arise. Oxidation with H2O2 was time and resource consuming. Getting reproducible results was hard and the reaction was not completed for grain-size analysis. Therefore the samples were also treated and carbonates were removed with HCl. It was also very important to remove biogenic silica by alkali treatment. The median values in grain-size spectra had trends towards finer grain size after treatment with KOH and observations with light microscope showed changes during treatments. The grain-size distribution measured by a laser particle sizer differed considerably between the five pre-treatment methods studied.

References

Allen, J. R. L. & Thornley, D. M. 2004. Laser granulometry of Holocene estuarine silts: effects of hydrogen peroxide treatment. Holocene, 14(2), 290–295.
doi:10.1191/0959683604hl681rr

Almeida, M. P., Andrade, J. S., Jr. & Herrmann, H. J. 2007. Aeolian transport of sand. Eur. Phys.
J. E
, 22, 195–200.
doi:10.1140/epje/e2007-00028-7

Andreola, F., Castellini, E., Manfredini, T. & Romagnoli, M. 2004. The role of sodium hexameta­phosphate in the dissolution process of kaolinite and kaolin. J. Eur. Ceram. Soc., 24(7), 2113–2124.
doi:10.1016/S0955-2219(03)00366-2

Battarbee, R. W. 1986. Diatom analysis. In Handbook of Holocene Palaeoecology and Palaeo­hydrology (Berglund, B. E., ed.), pp. 527–570. John Wiley & Sons, Toronto.

Battarbee, R. W., Jones, V. J., Flower, R. J., Cameron, N. G. & Bennion, H. 2001. Diatoms. In Tracking Environmnental Change Using Lake Sediments. Volume 3: Terrestrial, Algal and Siliceous Indicators (Smol, J. P., Birks, H. J. B. & Last, W. M., eds), pp. 155–202. Kluwer Academic Publishers, Dordrecht.

Blott, S. J. & Pye, K. 2006. Particle size distribution analysis of sand-sized particles by laser diffraction: an experimental investigation of instrument sensitivity and the effects of particle shape. Sedimentology, 53, 671–685.
doi:10.1111/j.1365-3091.2006.00786.x

Bohling, B. 2004. Variations in grain size analysis with a time-of-transition laser sizer (Galai CIS-50) using a gravitational flow system. Part. Part. Syst. Charact., 21(6), 455–462.
doi:10.1002/ppsc.200400915

Boyle, J. F. 2001. Inorganic geochemical methods in palaeolimnology. In Tracking Environmental Change Using Lake Sediments. Volume 2: Physical and Geochemical Methods (Last, M. L. & Smol, J. B., eds), pp. 83–141. Kluwer Academic Publishers, Dordrecht.

Buurman, P., Pape, Th., Reijneveld, J. A., de Jong, F. & van Gelder, E. 2001. Laser-diffraction and pipette-method grain sizing of Dutch sediments: correlations for fine fractions of marine, fluvial, and loess samples. Neth. J. Geosci., 80(2), 49–57.

Carver, R. E. (ed.) 1971. Procedures in Sedimentary Petrology. Wiley Interscience, New York.

Conley, D. J. 1998. An interlaboratory comparison for the measurement of biogenic silica in sediments. Mar. Chem., 63, 39–48.
doi:10.1016/S0304-4203(98)00049-8

Dominik, P. & Kaupenjohann, M. 2000. Simple spectrophotometric determination of Fe in oxalate and HCl soil extracts. Talant, 51, 701–707.
doi:10.1016/S0039-9140(99)00324-0

Gu, B., Melhorn, T. L., Liang, L. & McCarthy, J. F. 1996. Competitive adsorption, displacement and transport of organic matter on iron oxide. II: Displacement and transport. Geochim. Cosmochim. Acta, 60, 2977–2992.
doi:10.1016/0016-7037(96)00157-3

Hayter, E. J. & Pakala, C. V. 1989. Transport of inorganic contaminants in estuarial water. J. Coast. Res., 5, 217–230.

Heiri, O., Lotter, A. F. & Lemcke, G. 2001. Loss on ignition as method for estimating organic and carbonate content in sediments: reproducibility and comparability of results. J. Paleolimnol., 25, 101–110.
doi:10.1023/A:1008119611481

Kadey, F. L., Jr. 1983. Diatomite. In Industrial Rocks and Minerals (LeFond, S. J., Jr., ed.),
pp. 677–708. American Institute of Mining, Metallurgical, and Petroleum Engineers, New York.

Kim, J.-W., Furukawa, Y., Dong, H. & Newell, S. W. 2005. The effect of microbial Fe(III) reduction on smectite flocculation. Clay. Clay Miner., 53(6), 572–579.
doi:10.1346/CCMN.2005.0530603

Konert, M. & Vandenberghe, J. 1997. Comparison of layer grain size analysis with pipette and sieve analysis: a solution for the underestimation of the clay fraction. Sedimentology, 44, 523–535.
doi:10.1046/j.1365-3091.1997.d01-38.x

Last, W. M. 2001a. Mineralogical analysis of lake sediments. In Tracking Environmental Change Using Lake Sediments. Volume 2: Physical and Geochemical Methods (Last, M. L. & Smol, J. B., eds), pp. 143–187. Kluwer Academic Publishers, Dordrecht.

Last, W. M. 2001b. Textural analysis of lake sediments. In Tracking Environmental Change Using Lake Sediments Volume 2: Physical and Geochemical Methods (Last, M. L. & Smol, J. B., eds), pp. 41–81. Kluwer Academic Publishers, Dordrecht.

Lu, H. & An, Z. 1997. Pretreatment methods in loess-palaeosol granulometry. Chinese Sci. Bull., 42, 237–240.

Lyle, A. O. & Lyle, M. W. 2002. Determination of biogenic opal in pelagic marine sediments: a simple method revisited. In Proceedings of the Ocean Drilling Program, Initial Reports. Volume 199 (Lyle, M., Wilson, P. A., Janecek, T. R., et al., eds), pp. 1–21. College Station, TX (Ocean Drilling Program).

McCave, I. N. & Syvitski, J. P. M. 1991. Principles and methods of geological particle size analysis. In Principles, Methods, and Application of Particle Size Analysis (Syvitski, J. P. M., ed.),
pp. 3–21. Cambridge University Press, Cambridge.

McCave, I. N., Hall, I. R. & Bianchi, G. G. 2006. Laser vs. settling velocity differences in silt grain-size measurements: estimation of palaeocurrent vigour. Sedimentology, 53, 919–928.
doi:10.1111/j.1365-3091.2006.00783.x

Mikkelsen, O. A. & Pejrup, M. 2001. The use of a LISST-100 laser particle sizer for in-situ estimates of floc size, density and settling velocity. Geo-Mar. Lett., 20, 187–195.
doi:10.1007/s003670100064

Mikutta, R., Kleber, M., Kaiser, K. & Jahn, R. 2005. Review: removal of organic matter from soils using hydrogen peroxide, sodium hypochlorite and disodium peroxodisulfate. Soil Sci. Soc. Am. J., 69, 120–135.

Murray, M. R. 2002. Is laser particle size determination possible for carbonate-rich lake sediments? J. Paleolimnol., 27, 173–183.
doi:10.1023/A:1014281412035

Paterson, D. M. 1997. Biological mediation of sediment erodibility: ecology and physical dynamics. In Cohesive Sediments (Burt, N., Parker, R. & Watts, J., eds), pp. 215–229. John Wiley and Sons, Chichester.

Punning, J.-M., Terasmaa, J., Vaasma, T. & Kapanen, G. 2008. Historical changes in the concentrations of polycyclic aromatic hydrocarbons (PAHs) in Lake Peipsi sediments. Environ. Monit. Assess., 144, 1–3, 131–141.
doi:10.1007/s10661-007-9951-4

Reynolds, R. L., Rosenbaum, J. G., Rapp, J., Kerwin, M. W., Bradbury, J. P., Colman, S. C. & Adam, D. 2004. Record of Late Pleistocene glaciation and deglaciation in the southern Cascade Range. I: Petrologic evidence from lacustrine sediment in Upper Klamath Lake, southern Oregon. J. Paleolimnol., 31, 217–233.
doi:10.1023/B:JOPL.0000019230.42575.03

Roberts, J., Jepsen, R., Gotthard, D. & Lick, W. 1998. Effects of particle size and bulk density on erosion of quartz particles. J. Hydraul. Eng., 124(12), 1261–1267.
doi:10.1061/(ASCE)0733-9429(1998)124:12(1261)

Round, F. E., Crawford, R. M. & Mann, D. G. 1990. The Diatoms. Cambridge University Press, Cambridge.

Schumacher, B. A. 2002. Methods for the Determination of Total Organic Carbon (TOC) in Soils and Sediments. Ecological Risk Assessment Support Center, Office of Research and Development, US Environmental Protection Agency, Las Vegas.

Thonon, I., Roberti, J. R., Middelkoop, H., Van der Perk, M. & Burrough, P. A. 2005. In situ measurements of sediment settling characteristics in floodplains using a LISST-ST. Earth Surf. Process. Land., 30, 1327–1343.
doi:10.1002/esp.1239

Van Rijn, L. 1993. Principles of Sediment Transport in Rivers, Estuaries, and Coastal Seas. Aqua Publications, Amsterdam.

Walkley, A. & Black, I. A. 1934. An examination of the Degtjareff method for determining soil organic matter and a proposed modification of the chromic acid titration method. Soil Sci., 37, 29–38.
doi:10.1097/00010694-193401000-00003

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